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High field level crossing studies on spin dimers in the low dimensional quantum spin system NaT(CO)(HO) with T=Ni,Co,Fe,Mn
In this paper we demonstrate the application of high magnetic fields to study
the magnetic properties of low dimensional spin systems. We present a case
study on the series of 2-leg spin-ladder compounds
NaT(CO)(HO) with T = Ni, Co, Fe and Mn. In all
compounds the transition metal is in the high spin configuation. The
localized spin varies from S=1 to 3/2, 2 and 5/2 within this series. The
magnetic properties were examined experimentally by magnetic susceptibility,
pulsed high field magnetization and specific heat measurements. The data are
analysed using a spin hamiltonian description. Although the transition metal
ions form structurally a 2-leg ladder, an isolated dimer model consistently
describes the observations very well. This behaviour can be understood in terms
of the different coordination and superexchange angles of the oxalate ligands
along the rungs and legs of the 2-leg spin ladder. All compounds exhibit
magnetic field driven ground state changes which at very low temperatures lead
to a multistep behaviour in the magnetization curves. In the Co and Fe
compounds a strong axial anisotropy induced by the orbital magnetism leads to a
nearly degenerate ground state and a strongly reduced critical field. We find a
monotonous decrease of the intradimer magnetic exchange if the spin quantum
number is increased